Materials
The pressure vessel of a boiler is usually made of steel (or alloy steel), or historically of wrought iron. Stainless steel, especially of the austenitic types, is not used in wetted parts of boilers due to corrosion and stress corrosion cracking.[3] However, ferritic stainless steel is often used in superheater sections that will not be exposed to boiling water, and electrically heated stainless steel shell boilers are allowed under the European "Pressure Equipment Directive" for production of steam for sterilizers and disinfectors.[4]

In live steam models, copper or brass is often used because it is more easily fabricated in smaller size boilers. Historically, copper was often used for fireboxes (particularly for steam locomotives), because of its better formability and higher thermal conductivity; however, in more recent times, the high price of copper often makes this an uneconomic choice and cheaper substitutes (such as steel) are used instead.

For much of the Victorian "age of steam", the only material used for boilermaking was the highest grade of wrought iron, with assembly by rivetting. This iron was often obtained from specialist ironworks, such as at Cleator Moor (UK), noted for the high quality of their rolled plate and its suitability for high-reliability use in critical applications, such as high-pressure boilers. In the 20th century, design practice instead moved towards the use of steel, which is stronger and cheaper, with welded construction, which is quicker and requires less labour. It should be noted, however, that wrought iron boilers corrode far slower than their modern-day steel counterparts, and are less susceptible to localized pitting and stress-corrosion. This makes the longevity of older wrought-iron boilers far superior to those of welded steel boilers.

Cast iron may be used for the heating vessel of domestic water heaters. Although such heaters are usually termed "boilers" in some countries, their purpose is usually to produce hot water, not steam, and so they run at low pressure and try to avoid boiling. The brittleness of cast iron makes it impractical for high-pressure steam boilers.

Energy
The source of heat for a boiler is combustion of any of several fuels, such as wood, coal, oil, or natural gas. Electric steam boilers use resistance- or immersion-type heating elements. Nuclear fission is also used as a heat source for generating steam, either directly (BWR) or, in most cases, in specialised heat exchangers called "steam generators" (PWR). Heat recovery steam generators (HRSGs) use the heat rejected from other processes such as gas turbine.

Boiler efficiency
there are two methods to measure the boiler efficiency 1) direct method 2) indirect method

Direct method -direct method of boiler efficiency test is more usable or more common

boiler efficiency =Q*(Hg-Hf)/q*GCV *100 Q =Total steam flow Hg= Enthalpy of saturated steam in k cal/kg Hf =Enthalpy of feed water in kcal/kg q= quantity of fuel use in kg/hr GCV =gross calorific value in kcal/kg like pet coke (8200 kcal/KG)

indirect method -to measure the boiler efficiency in indirect method, we need a following parameter like

Ultimate analysis of fuel (H2,S2,S,C moisture constraint, ash constraint)
percentage of O2 or CO2 at flue gas
flue gas temperature at outlet
ambient temperature in deg c and humidity of air in kg/kg
GCV of fuel in kcal/kg
ash percentage in combustible fuel
GCV of ash in kcal/kg
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Configurations
Boilers can be classified into the following configurations:

Pot boiler or Haycock boiler/Haystack boiler: a primitive "kettle" where a fire heats a partially filled water container from below. 18th century Haycock boilers generally produced and stored large volumes of very low-pressure steam, often hardly above that of the atmosphere. These could burn wood or most often, coal. Efficiency was very low.
Flued boiler with one or two large flues—an early type or forerunner of fire-tube boiler.

Diagram of a fire-tube boiler
Fire-tube boiler: Here, water partially fills a boiler barrel with a small volume left above to accommodate the steam (steam space). This is the type of boiler used in nearly all steam locomotives. The heat source is inside a furnace or firebox that has to be kept permanently surrounded by the water in order to maintain the temperature of the heating surface below the boiling point. The furnace can be situated at one end of a fire-tube which lengthens the path of the hot gases, thus augmenting the heating surface which can be further increased by making the gases reverse direction through a second parallel tube or a bundle of multiple tubes (two-pass or return flue boiler); alternatively the gases may be taken along the sides and then beneath the boiler through flues (3-pass boiler). In case of a locomotive-type boiler, a boiler barrel extends from the firebox and the hot gases pass through a bundle of fire tubes inside the barrel which greatly increases the heating surface compared to a single tube and further improves heat transfer. Fire-tube boilers usually have a comparatively low rate of steam production, but high steam storage capacity. Fire-tube boilers mostly burn solid fuels, but are readily adaptable to those of the liquid or gas variety.

Diagram of a water-tube boiler.
Water-tube boiler: In this type, tubes filled with water are arranged inside a furnace in a number of possible configurations. Often the water tubes connect large drums, the lower ones containing water and the upper ones steam and water; in other cases, such as a mono-tube boiler, water is circulated by a pump through a succession of coils. This type generally gives high steam production rates, but less storage capacity than the above. Water tube boilers can be designed to exploit any heat source and are generally preferred in high-pressure applications since the high-pressure water/steam is contained within small diameter pipes which can withstand the pressure with a thinner wall.
Flash boiler: A flash boiler is a specialized type of water-tube boiler in which tubes are close together and water is pumped through them. A flash boiler differs from the type of mono-tube steam generator in which the tube is permanently filled with water. In a flash boiler, the tube is kept so hot that the water feed is quickly flashed into steam and superheated. Flash boilers had some use in automobiles in the 19th century and this use continued into the early 20th century. .

1950s design steam locomotive boiler, from a Victorian Railways J class
Fire-tube boiler with Water-tube firebox. Sometimes the two above types have been combined in the following manner: the firebox contains an assembly of water tubes, called thermic siphons. The gases then pass through a conventional firetube boiler. Water-tube fireboxes were installed in many Hungarian locomotives,[citation needed] but have met with little success in other countries.
Sectional boiler. In a cast iron sectional boiler, sometimes called a "pork chop boiler" the water is contained inside cast iron sections.[citation needed] These sections are assembled on site to create the finished boiler.
Safety
See also: Boiler explosion
To define and secure boilers safely, some professional specialized organizations such as the American Society of Mechanical Engineers (ASME) develop standards and regulation codes. For instance, the ASME Boiler and Pressure Vessel Code is a standard providing a wide range of rules and directives to ensure compliance of the boilers and other pressure vessels with safety, security and design standards.[5]

Historically, boilers were a source of many serious injuries and property destruction due to poorly understood engineering principles. Thin and brittle metal shells can rupture, while poorly welded or riveted seams could open up, leading to a violent eruption of the pressurized steam. When water is converted to steam it expands to over 1,000 times its original volume and travels down steam pipes at over 100 kilometres per hour. Because of this, steam is a great way of moving energy and heat around a site from a central boiler house to where it is needed, but without the right boiler feed water treatment, a steam-raising plant will suffer from scale formation and corrosion. At best, this increases energy costs and can lead to poor quality steam, reduced efficiency, shorter plant life and unreliable operation. At worst, it can lead to catastrophic failure and loss of life. Collapsed or dislodged boiler tubes can also spray scalding-hot steam and smoke out of the air intake and firing chute, injuring the firemen who load the coal into the fire chamber. Extremely large boilers providing hundreds of horsepower to operate factories can potentially demolish entire buildings.[6]

A boiler that has a loss of feed water and is permitted to boil dry can be extremely dangerous. If feed water is then sent into the empty boiler, the small cascade of incoming water instantly boils on contact with the superheated metal shell and leads to a violent explosion that cannot be controlled even by safety steam valves. Draining of the boiler can also happen if a leak occurs in the steam supply lines that is larger than the make-up water supply could replace. The Hartford Loop was invented in 1919 by the Hartford Steam Boiler and Insurance Company as a method to help prevent this condition from occurring, and thereby reduce their insurance claims.[7][8]

Superheated steam boiler

A superheated boiler on a steam locomotive.
Main article: Superheater
Most boilers produce steam to be used at saturation temperature; that is, saturated steam. Superheated steam boilers vaporize the water and then further heat the steam in a superheater. This provides steam at much higher temperature, but can decrease the overall thermal efficiency of the steam generating plant because the higher steam temperature requires a higher flue gas exhaust temperature.[citation needed] There are several ways to circumvent this problem, typically by providing an economizer that heats the feed water, a combustion air heater in the hot flue gas exhaust path, or both. There are advantages to superheated steam that may, and often will, increase overall efficiency of both steam generation and its utilization: gains in input temperature to a turbine should outweigh any cost in additional boiler complication and expense. There may also be practical limitations in using wet steam, as entrained condensation droplets will damage turbine blades.

Superheated steam presents unique safety concerns because, if any system component fails and allows steam to escape, the high pressure and temperature can cause serious, instantaneous harm to anyone in its path. Since the escaping steam will initially be completely superheated vapor, detection can be difficult, although the intense heat and sound from such a leak clearly indicates its presence.

Superheater operation is similar to that of the coils on an air conditioning unit, although for a different purpose. The steam piping is directed through the flue gas path in the boiler furnace. The temperature in this area is typically between 1,300 and 1,600 °C (2,372 and 2,912 °F). Some superheaters are radiant type; that is, they absorb heat by radiation. Others are convection type, absorbing heat from a fluid. Some are a combination of the two types. Through either method, the extreme heat in the flue gas path will also heat the superheater steam piping and the steam within. While the temperature of the steam in the superheater rises, the pressure of the steam does not and the pressure remains the same as that of the boiler.[9] Almost all steam superheater system designs remove droplets entrained in the steam to prevent damage to the turbine blading and associated piping.

Supercritical steam generator

Boiler for a power plant.
Main article: Supercritical steam generator
Supercritical steam generators are frequently used for the production of electric power. They operate at supercritical pressure. In contrast to a "subcritical boiler", a supercritical steam generator operates at such a high pressure (over 3,200 psi or 22 MPa) that the physical turbulence that characterizes boiling ceases to occur; the fluid is neither liquid nor gas but a super-critical fluid. There is no generation of steam bubbles within the water, because the pressure is above the critical pressure point at which steam bubbles can form. As the fluid expands through the turbine stages, its thermodynamic state drops below the critical point as it does work turning the turbine which turns the electrical generator from which power is ultimately extracted. The fluid at that point may be a mix of steam and liquid droplets as it passes into the condenser. This results in slightly less fuel use and therefore less greenhouse gas production. The term "boiler" should not be used for a supercritical pressure steam generator, as no "boiling" occurs in this device.
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